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Superhalogen species are kinds of molecular clusters consisting of highly electronegative ligands and central atoms 1a.The most important characteristics of superhalogens is the extremely high electron affinities (EA)1b which leads to great potential for applications1a,1b in the fields of synthesis of new chemical compounds,new dopants to increase the electrical conductivity of polymers and production of organic metal,organic superconductors and nonlinear optical materials.