Sodium sulfinates have recently been demonstrated as electrophilic partners in transition-metal-catalyzed desulfitative C-C cross-coupling reactions,in organic synthesis.
Lactone marasmane sesquiterpenes(such as Ⅰ,Ⅱ and Ⅲ shown in scheme 1A) were isolated from the fruiting bodies of Russula foetens widely distributed in China.
Water was used as promoting medium for three-component reactions of alkylglyoxals,1,3-dicarbonyl compounds and a nucleophile,which produces 1,4-diketone scaffolds in a straightforward way.
Demands of methods for rapidly screening new reactions that can produce complex and diverse drug-like small molecules continue to stimulate the design and development of conceptually innovative strate
Recently,Rh(Ⅲ)-catalyzed C-H activation assisted by an oxidizing directing group has evolved to a mild and redox-economic strategy for synthetic chemistry.
Rh(Ⅲ) catalysts stand out with high activity,high selectivity,broad scope and functional-group and have been increasingly employed in C-H activation and subsequent coupling with variousunsaturated mol
Iron,being one of the most abundant metals,becomes particularly attractive for CDC reactions because of its low price,nontoxicity,and environmentally benign character.