【摘 要】
：
利用醋酸镉、2,2-二羧酸偶氮苯(H2L)和含N 辅助配体分别进行水热反应,通过调控辅助配体的种类,合成了三个结构各异的金属配位聚合物[CdL(bpy)]n(1),{[Cd4L4(bpe)(H2O)2]
【机 构】
：
安阳师范学院化学化工学院,河南安阳455000
【出 处】
：
2015年中西部地区无机化学化工学术研讨会
论文部分内容阅读
利用醋酸镉、2,2-二羧酸偶氮苯(H2L)和含N 辅助配体分别进行水热反应,通过调控辅助配体的种类,合成了三个结构各异的金属配位聚合物[CdL(bpy)]n(1),{[Cd4L4(bpe)(H2O)2]·2H2O}n(2)和[CdL(bpp)]n(3)[bpy = 4,4-bipyridine,bpe = 1,2-bis(4-pyridyl)ethylene,bpp =1,3-bis(4-pyridyl)propane]。结构分析表明,化合物1是一个具有三重穿插的diamond 框架结构。化合物2是一个三维的柱-层结构。化合物3以螺旋的[Cd(bpp)]n 和[CdL]n 链为构建单元,得到一个三维结构。在室温下,测试了它们的荧光性质。
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