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Fe-doped Bi2O3 microspheres (Fe-Bi2O3) were fabricated by a facile hydrothermal method.The Fe-Bi2O3 sample was characterized by X-ray powder diffraction (XRD), X-ray photoelectron spectroscopy (XPS),transmission electron microscopy (FE-SEM), Fourier transform infrared (FTIR), Energy Dispersive Spectrometer (EDS) and UV-vis diffuse reflectance spectroscopy were employed to study the structures, morphologies and optical properties.