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In situ [2+3] cycloaddition reaction of 4-tetrazolemethyl pyridine and NaN3 in the presence of Lewis acid ZnCl2/ZnBr2,water and ethanol affords two novel 2D layered structures,[Zn(Tzmp)Cl]n(1)and [Zn(Tzmp)Br]n(2)(HTzmp = 4-tetrazolemethyl pyridine)[1-3].