论文部分内容阅读
脱氢反应为有机化合物的氧化以及进一步转化提供了绿色的途径[1]。脱氢反应的化学选择性控制一般依赖于发展不同的催化剂。本报告将介绍我们近期发展的几个脱氢反应中化学选择性控制的新策略：动力学控制的化学选择性[2]；气体氛围控制的化学选择性[3]；接力催化策略调控的化学选择性[4-5]。
脱氢反应中的化学选择性控制
【摘 要】
：
脱氢反应为有机化合物的氧化以及进一步转化提供了绿色的途径[1]。脱氢反应的化学选择性控制一般依赖于发展不同的催化剂。本报告将介绍我们近期发展的几个脱氢反应中化
【出 处】
：
第十二届全国物理有机化学学术会议
【发表日期】
：
2017年10期
其他文献
Computational Insights into the Gold-Catalyzed Hydroamination of Methylenecyclopropanes with Sulfona
Transition metal-catalyzed reactions of methylenecyclopropanes(MCPs)have attracted increasing research attention over the past two decades since MCPs have h
会议
Computational Studies on the Divergent Reactions between α-Imino Rhodium Carbenoids and 1,3-Diketone
The characteristic imine functionality adjacent to the rhodium carbenoid center[1] renders these carbene species especially useful in the synthesis of vario
会议
Mechanistic Insights into the Rh(Ⅱ)-Catalyzed Ring Expansion of Aryl Azides to Access N-heterocycles
Recently,the direct amination1 of C-H bonds to construct C-N bonds via metal nitrenes2 catalyzed by transition metal catalysts has attracted significant int
会议
A DFT Study on the Pd(0)-Catalyzed Reaction of Cyclopropene Derivatives with Pronucleophiles to Form
Transition-metal-catalyzed reactions of cyclopropene derivatives have attracted great research interests due to the presence of strained and unsaturated thr
会议
Mechanistic Insights into Ru-Catalyzed Regioselective Cycloisomerization of Aromatic Homo-and Bis-Ho
Metal catalyzed cycloisomerization reactions towards the formation of new C-X bonds(where X = C,O,N etc.)has attracted significant attention in recent years
会议
The global aromaticity of oxygen-,imino-,and sulfur-bridged [18] annulenes was investigated using the topological resonance energy(TRE),percentage topologic
会议
Spiroindolenines and related polycyclic indoles are attractive scaffolds that are widely found in natural products.1 In the past few years,we have developed a s
会议
本文介绍了近期在多组分微米/纳米共晶材料的组装及光功能研究。与单组分材料相比，多组分体系具备较多优势，通过不同制备方法(如溶液法，固相法，气相法等)可以得到结构和功能