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5. Why do dirhodium vinylcarbenes having different steric hindrance lead to totally diverse products in

Why do dirhodium vinylcarbenes having different steric hindrance lead to totally diverse products in

来源 :The 15th ICQC International Congress of Quantum Chemistry(第1 | 被引量 : 0次 | 上传用户：pgqing

【摘 要】

：

Recently,through the use of chiral bulky-Rh2L4 catalyst,highly enantioselective [3+2]-cycloaddition between nitrones and vinyldiazoacetates(reaction a) has been achieved[1].

【作 者】

：

X.Yang Y.S.Yang P.Xu Y.Xue 

【机 构】

：

College of Chemistry,Key Lab of Green Chemistry and Technology in Ministry of Education,Sichuan Univ

【出 处】

：

The 15th ICQC International Congress of Quantum Chemistry(第1

【发表日期】

：

2015年5期

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Recently,through the use of chiral bulky-Rh2L4 catalyst,highly enantioselective [3+2]-cycloaddition between nitrones and vinyldiazoacetates(reaction a) has been achieved[1].

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