Greenhouse gas CO2 has become a serious problem for human beings. The hydrate technology has been considered as a possible approach to sequester CO2. In this work, the lateral growth rates of a CO2 hydrate film in aqueous NaCl solutions of different concentrations were measured by means of suspending a single gas bubble in liquid. The results show that the film growth rates depended on not only the driving force, but also the NaCl concentration, and the film growth rates decreased with the increasing NaCl concentration. The simple relationship vf ∝ΔT5/2 could be used to correlate the hydrate film growth rate of a CO2 + NaCl + water system by introducing a NaCl concentration-dependent coefficient. The film thickness was investigated experimentally and evaluated theoretically; the results show that it became thicker at a higher NaCl concentration when the temperature and pressure were specified. In addition, a series of interesting phenomena, such as the occurrence of double hydrate films, were displayed and discussed. Greenhouse gas CO2 has become a serious problem for human beings. The hydrate technology has been considered as a possible approach to sequester CO2. In this work, the lateral growth rates of a CO2 hydrate film in aqueous NaCl solutions of different concentrations were measured by means of suspending a single gas bubble in liquid. The results show that the film growth rates depended only on driving forces, but also the NaCl concentration, and the film growth rates decreased with increasing NaCl concentration. The simple relationship vf αΔT5 / 2 could be used to correlate the hydrate film growth rate of a CO2 + NaCl + water system by introducing a NaCl concentration-dependent coefficient. The film thickness was investigated experimentally and as theoretically; the results show that it became thicker at a higher NaCl concentration when the temperature and pressure were specified. In addition, a series of interesting phenomena, such as the occurrence of double hydrate f ilms, were displayed and discussed.