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The reaction of CoCl2·6H2O with 2,6-bis(N,N’-bis(2,6-diisopropyl-4-(2,3-dimethy-oxyl-benzoylamide)phenylimino))pyridine(L) afforded the complex [CoCl2L],which was fully characterized by elemental analysis,UV-vis,IR spectroscopy,fluorescence,and X-ray diffraction analysis.The compound is of triclinic system,space group P1 with a = 13.058(3),b = 13.798(3),c = 16.695(3) ,α = 98.191(3),β = 102.792(3),γ = 101.820(3)°,V = 2815.0(9) 3,Z = 2,F(000) = 1122,μ = 0.45 mm-1,R = 0.061 and wR = 0.1349 for 9842 observed reflections(Ⅰ > 2σ(Ⅰ)).The Co(Ⅱ) center adopts a distorted square-pyramidal coordination geometry.The extended structure shows a one-dimensional zigzag double chain linked by hydrogen bonds and π-π stacking interactions.
The reaction of CoCl2 · 6H2O with 2,6-bis (2,6-diisopropyl-4- (2,3-dimethy- oxyl-benzoylamide) phenylimino) CoCl2L], which was fully characterized by elemental analysis, UV-vis, IR spectroscopy, fluorescence and X-ray diffraction analysis. The compound is of triclinic system, space group P1 with a = 13.058 (3), b = 13.798 , c = 16.695 (3) , α = 98.191 (3), β = 102.792 (3), γ = 101.820 (3) °, V = 2815.0 1122, μ = 0.45 mm-1, R = 0.061 and wR = 0.1349 for 9842 observed reflections (Ⅰ> 2σ (Ⅰ)). The Co (Ⅱ) center adopts a distorted square-pyramidal coordination geometry. -dimensional zigzag double chain linked by hydrogen bonds and π-π stacking interactions.