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本文提出了一个[Co(三元胺)(二元胺)Cl]2+型的配合物及其异构体的重排机理模型,它包含了所有异构体间的转换关系.这一模型表明面式异构体在重排过程中的重要性,利用对映异构体旋光性质及其可能的变化提出了可能存在一与经典模式不同的中间休假设。
In this paper, we propose a model for the rearrangement of [Co (triamine) (diamine) Cl] 2+ complexes and their isomers, which contains the conversion between all isomers. This model shows the importance of surface isomers in the rearrangement process. Using the optical properties of enantiomers and their possible variations, it is proposed that there may be an intermediate hypothesis different from the classical one.