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On the frontier of organic chemistry in recent years,research on single-electron-transfer(SET)reactions has been exceedingly active and abundantly rewarded.The present workis designed with the idea or objective to apply in conjunction SET mechanistic concepts andone of our generalizations(“β-electron pair rule”)on the non-radical reactions of theC-F bond.The latter in its simplest form can be stated as:Under non-acidic and non-drastic conditions a C-F bond of the perfluoro or polyfluoro type will not participate either
On the frontier of organic chemistry in recent years, research on single-electron-transfer (SET) reactions has been exceedingly active and abundantly rewarded. The present work designed designed with the idea or objective to apply in conjunction SET mechanistic concepts and one of our generalizations ( “Β-electron pair rule”) on the non-radical reactions of theC-F bond. The latter in its simplest form can be stated as: Under non-acidic and non-drastic conditions a CF bond of the perfluoro or polyfluoro type will not participate either