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合成了一种新的铜配合物[Cu(C3N2H3)2(H2NC6H4SO3)2(H2O)2]·2H2O,经元素分析和X-射线衍射得该化合物的分子式为C18H26CuN6O10S2,该晶体属单斜晶系,空间群为P 121／n,晶胞参数为a=7．2928(15) A,b=15．635(3)A,c=11．361(2)A;α=γ=90°,β=104．94(3)°;Z=2;DC=1．629 mg／m3;F(000)= 634;对于可观测衍射点的R1=0．0548,wR2=0．1516,S=1．014;最终差图中最大电子密度峰值和洞值分别为0．968e．A-3和-0．465e．A-3．两个对氨基苯磺酸和两个吡唑各自提供一个N原子、另有两个H2O分别与 Cu2+配位,Cu2+的配位多面体为畸变八面体．
A new copper complex [Cu (C3N2H3) 2 (H2NC6H4SO3) 2 (H2O) 2] · 2H2O was synthesized and characterized by elemental analysis and X-ray diffraction. The formula of the compound is C18H26CuN6O10S2. The crystal is monoclinic , The space group is P 121 / n, the unit cell parameters are a = 7.2928 (15) A, b = 15.635 (3) A, c = 11.361 (2) A; β = 104.94 (3) °; Z = 2; DC = 1.629 mg / m3; F (000) = 634; R1 = 0.0548 for an observable diffraction point, 1.014. The maximum electron density peak value and hole value in the final difference graph are 0.968e. A-3 and -0.465e. A-3. Two p-aminobenzenesulfonic acids and two pyrazoles each provide one N atom, and the other two H20 are coordinated with Cu2 + respectively, and the coordination polyhedron of Cu2 + is a distorted octahedron.