叙述了碳三液相催化加氯动力学实验研究情况;考察了空速、氢炔比和温度等操作条件对MAPD(丙炔、丙二烯)转化率和碳三加氢选择性的影响;并对碳三加氢反应也进行了动力学探索研究,提出了加氢生成丙烯和丙烯加氢生成丙烷的宏观动力学模型。 The kinetics of chlorination in C3 liquid phase was described. The effects of operating conditions such as space velocity, hydrogen-to-alkane ratio and temperature on the conversion of MAPD (propargylidene and propadiene) and the selectivity to C3H3 were investigated. In addition, kinetic studies on the hydrogenation of carbon 3 have also been carried out. A macroscopical kinetic model for the hydrogenation of propylene and propylene to propane has been proposed.