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采用常规方法合成了2个Anderson型多金属氧酸盐Na3H3[C4FN3OH4]6[TeMo6O24].8H2O(Ⅰ)和Na2H[C4FN3OH4]2[Al(OH)6Mo6O18].13H2O(Ⅱ).通过元素分析、红外光谱、热重分析、X射线单晶衍射对其进行了表征.结果表明:2个化合物均属于三斜晶系,P-1空间群;化合物Ⅰ的晶胞参数a=1.106 91(10)nm,b=1.148 99(10)nm,c=1.358 07(12)nm,α=71.63(2)°,β=66.25(10)°,γ=67.44(2)°,V=1.433 4(2)nm3,Z=1,R1=0.074 8,wR2=0.127 9;化合物Ⅱ的晶胞参数a=0.687 88(4)nm,b=1.168 45(7)nm,c=1.306 90(8)nm,α=81.339 0(10)°,β=77.890 0(10)°,γ=79.548 0(10)°,V=1.003 07(10)nm3,Z=1,R1=0.031 4,wR2=0.099 5.
Two Anderson-type polyoxometalates Na3H3 [C4FN3OH4] 6 [TeMo6O24] .8H2O (Ⅰ) and Na2H [C4FN3OH4] 2 [Al (OH) 6Mo6O18] 13H2O were synthesized by conventional methods. The results show that the two compounds belong to the triclinic and P-1 space group, and the unit cell parameter a of Compound I is 1.106 91 (10) α = 71.63 (2) °, β = 66.25 (10) °, γ = 67.44 (2) °, V = 1.433 4 (2 ) nm3, Z = 1, R1 = 0.074 8, and wR2 = 0.127 9. The unit cell parameters of compound Ⅱ a = 0.687 88 (4) nm and b = 1.168 45 (7) nm, α = 81.339 0 (10) °, β = 77.890 0 (10) °, γ = 79.548 0 (10) °, V = 1.003 07 (10) nm3, Z = 1, R1 = 0.031 4, wR2 = 0.0995.