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新合成了亚酞菁铜.把1,3-二亚胺基异吲哚啉、钼酸铵和二水乙酸合铜在喹啉里加热,加入催化剂量的1,8-二氮杂-双环(5,4,O)十一碳烯-7(DBU)进行反应.反应完毕后,通过索氏提取,然后用柱色层分离,得到灰褐色产物.通过质谱分析和元素分析数据证实,灰褐色产物就是目标化合物亚酞菁铜.根据亚酞菁铜分子裂解质谱图,还初步分析了亚酞菁铜分子的裂解过程,首次给出亚酞菁铜合成的反应机理.
A new copper subphthalocyanine was synthesized by heating 1,3-diiminoisoindoline, ammonium molybdate and copper acetate diacetate in quinoline, adding a catalytic amount of 1,8-diaza-bicyclo (5,4, 0) undecene-7 (DBU) were reacted in the same reaction system as in Example 1. The reaction was completed by Soxhlet extraction and then separated by column chromatography to obtain a beige product. Mass spectrometry and elemental analysis confirmed that the ash The brown product is the target compound of sub-phthalocyanine copper.According to the sub-phthalocyanine molecular cleavage mass spectrometry, the sub-phthalocyanine copper molecule cleavage process is also analyzed initially, and the reaction mechanism of sub-phthalocyanine copper synthesis is given for the first time.