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A tellurite fibre of TeO2-ZnO-La2Os-Li2O glass codoped with 20000 ppm ytterbium and 5000 ppm erbium was fabricated by the suction casting and rod-in-tube technologies. The absorption spectrum of Er3+/Yb3+ -codoped bulk glass has been measured. From the Judd-Ofelt intensity parameters, the spontaneous emission probability and radiative lifetime τrad of Er3+:4I13/2 →4I15/2 transition for the bulk glass have been calculated. The emission fluorescence spectra and lifetimes around 1.5μm, and subsequent upconversion fluorescence in the range of 500-700nm were measured in fibres and compared with those in bulk glass. The changes in amplified spontaneous emission with fibre length and pumping power was also measured. It was found that the emission spectrum from erbium in fibres is almost twice as broad as the corresponding spectrum in bulk glass when pumped at 980nm.