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5. The Preparation of α-Phosphonovinylzirconocenes and their Application in the Stereospecific Synthesi

The Preparation of α-Phosphonovinylzirconocenes and their Application in the Stereospecific Synthesi

来源 :中国化学快报 | 被引量 : 0次 | 上传用户：lidongying

【摘 要】

：

Hydrozirconation of 1-alkylnylphosphonates gives the organozirconium(IV) complexes 2 in syn-addition way. Complexs 2 was trapped with NCS,NBS or I2 to afford st

【作 者】

：

Zheng Chang XIONG Lu Ling WU X 

【机 构】

：

Department of Chemistry, State key Laboratory of Organometallic Chemistry

【出 处】

：

中国化学快报

【发表日期】

：

2004年期

【关键词】

：

1-Alkynylphosphonates hydrozirconation α-halo-1-alkenylphosphonates 

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论文部分内容阅读

Hydrozirconation of 1-alkylnylphosphonates gives the organozirconium(IV) complexes 2 in syn-addition way. Complexs 2 was trapped with NCS,NBS or I2 to afford stereodifinedα-halo-1-alkenylphosphonates in moderate to high yields.

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