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采用金相显微镜和扫描电镜分析了Q345E钢Φ800 mm铸坯(/%:0.15C,0.27Si,1.37Mn,0.009P,0.001S,0.03Nb,0.04V,0.030A1,0.008 ON)表面网状裂纹,得出结晶器壁和凝固坯壳之间保护渣膜厚度不均匀,使坯壳局部受挤压,产生凹坑,冷却速度降低,产生热应力裂纹。通过将保护渣碱度(CaO)/(SiO2)从1.03提高到1.15,熔点从1 235℃降至1 210℃,1 300℃粘度从0.87 Pa·s提高到1.10 Pa·s,使Φ800