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Angew.Chem.Int.Ed.2014,53,1822~1826钯催化有机硼酸与卤化物的反应,即Suzuki-Miyaura交叉偶联反应是应用最广泛的C—C键形成方法之一.为了更有效地合成更复杂的化合物,多官能团底物的制备和选择性反应就显得非常重要.多卤化物的研究已经广为人知,而反应性可以区分的多硼化合物则更具有挑战性,仅在近年来引起合成化学家的关注.文献中一些双硼化合物都是从含有其它官能团的有机硼制得,因而制备步骤繁琐,限制了其应用范围.西安交通大学前沿科学技术研究院有机
Angew. Chem. Int. Ed. 2014, 53, 1822-1826 Palladium catalyzes the reaction of organoboronic acids with halides, ie the Suzuki-Miyaura cross-coupling reaction is one of the most widely used C-C bond formation methods. Synthesis of more complex compounds, multi-functional substrate preparation and selective reaction is very important.However, the study of polyhalides has been widely known, while the polyborane compounds with more distinguishable reactivity are more challenging and only caused in recent years Synthesis of chemists attention.Double boron compounds in the literature are from the other functional groups containing organic boron prepared, and thus preparation steps cumbersome, limiting its scope of application. Xi’an Jiaotong University Institute of Advanced Science and Technology organic