An Interpenetrated Three-dimensional Framework Sodium Lanthanide Carboxylate Based on[Ho4(μ3-OH)4]8+

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A novel sodium holmium carboxylate compound,namely Na4Ho4(μ3-OH)4(1,4-BDC6·6.25G2I(1,4-BDC=1,4-benzenedicarboxylate),has been solvothermally synthesized and structurally characterized.The structure features a two-fold interpenetrated three-dimensional open-framework constructed by the[Ho4(μ3-OH)4]8+clusters bridged by 1,4-BDC ligands.The Na+ions and lattice water molecules are located in the channels.The structure is further stabilized by hydrogen-bonding and π-π stacking interactions.The thermal stability of the compound has been investigated via thermogravimetric analysis.
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