很多分子固体和低维固体在室温或低热温度条件下可发生固相反应［１，２］，甚至可以在短时间内完成［３，４］．我们已成功地用低热固相合成法合成了２００多个化合物，其中大多数为结构新颖的原子簇化合物［５～７］．同时，在每个阶段实验事实的基础上，指出固－固相反... Many molecular solids and low-dimensional solids can undergo solid phase reactions at room or low temperatures [1, 2] and can even be completed in a short period of time [3,4]. We have successfully synthesized more than 200 compounds by low-temperature solid-phase synthesis, most of which are novel cluster compounds [5-7]. At the same time, based on the experimental facts in each stage, it is pointed out that the solid-solid phase ...