论文部分内容阅读
在二氯甲烷中氩气保护下用氧化碘苯氧化ClMn~ⅢT(P—R)PP,其中R=-OCH_3或-CO_2CH_3,合成了氧络锰(Ⅳ)卟啉配合物,O=Mn~ⅣT(P—R)PP。它们的可见吸收光谱在波长为430nm处有强的Soret带和525nm处有宽的肩吸收带。红外光谱在波数为1060cm~(-1)处有Mn=O的特征吸收峰。它们具有氧化碳氢化合物的性质。
In the presence of methylene chloride, the oxidative oxidation of ClMn ~ ⅢT (P-R) PP with iodobenzene was carried out under the protection of argon in dichloromethane. O ~ Mn ~ (Ⅳ) porphyrin complexes were synthesized by the reaction of R = -OCH_3 or -CO_2CH_3. IVT (P-R) PP. Their visible absorption spectra have a strong Soret band at a wavelength of 430 nm and a wide shoulder band at 525 nm. The infrared spectrum has the characteristic absorption peak of Mn = O at the wavenumber of 1060cm ~ (-1). They have the property of oxidizing hydrocarbons.