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根据色谱热力学理论,推导出超临界流体色谱中同系物的容量因子对数与常沸点间的直线方程;不同温度下同系物的诸直线存在共同交点,提出了交点方程。用大量试验数据进行检验,获得满意结果。
According to the chromatographic thermodynamics theory, the linear equations of the logarithm of capacity factor and the normal boiling points of the homologues in the supercritical fluid chromatography were deduced. The intersections of the straight lines of the homologues were found at different temperatures. Test with a large number of test data to obtain satisfactory results.