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研究了团体起强碱催化的β-蒎烯异构化反应。在固体超强碱的作用下β-蒎烯异构化反应可在空温下发生,通过此反应可高收率地获得α-蒎烯。实验证明,在β-蒎烯异构化反应中β-蒎烯的转化率和α-蒎烯的选择性均能达到近100%的程度。同时也对影响异构化反应的主要因素进行了探讨。
The group catalyzed β-pinene isomerization catalyzed by strong bases. Under the action of solid superbase, β-pinene isomerization reaction can take place at room temperature. Through this reaction, α-pinene can be obtained with high yield. Experiments show that β-pinene isomerization in the β-pinene conversion and α-pinene selectivity can reach nearly 100% degree. At the same time, the main factors influencing the isomerization reaction are also discussed.