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用 H2 S O4 K2 Cr2 O7 氧化有机碳, 在120℃以上, Cl- 对尿素氧化起催化作用,造成明显的正干扰。沸水浴重铬酸钾法氧化有机碳,在100℃左右,尿素碳不被氧化, Cl- 可定量扣除, 有机碳氧化率为82% 左右, 校正后回收率达1017% , 测定值变异系数 C V≤28% 。此法适合有机无机肥料中有机碳的测定。
Oxidation of organic carbon with H2S04-K2Cr2O7 catalyzed the oxidation of urea at temperatures above 120 ° C, resulting in significant positive interference. Boiling water bath potassium dichromate oxidation of organic carbon at about 100 ℃, urea is not oxidized, Cl-quantitative deduction, organic carbon oxidation rate of about 82%, the corrected recovery of 101.7%, the measured value of variation Coefficient C V ≦ 2 8%. This method is suitable for determination of organic carbon in organic and inorganic fertilizers.