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本文报道了二（２－氨乙基）－１，３－丙二胺［缩写为（２，３，２）］与镍的两个新配合物：［（２，３，２）Ｎｉ（ＩｍＨ）２］（ＣｌＯ４）２和［（２，３，２）２Ｎｉ２（Ｉｍ）］（ＣｌＯ４）３的合成和晶体结构（其中ＩｍＨ是咪唑）。配合物［（２，３，２）Ｎｉ（ＩｍＨ２）］（ＣｌＯ４）２属于正交晶系，空间群Ｐｎａ２１，晶胞参数为：ａ＝１６．７９８（３），ｂ＝１５．７２４（３），ｃ＝８．８９１（２），Ｚ＝２。Ｒ１＝０．０５６６，ｗＲ２＝０．０６５９。在配合物正离子中，Ｎｉ与（２，３，２）的四个配位Ｎ原子和两个咪唑的两个配位Ｎ原子构成ＮｉＮ６的八面体配位构型，（２，３，２）采取顺式构象。配合物［（２，３，２）２Ｎｉ２（Ｉｍ）］（ＣｌＯ４）３属于单斜晶系，空间群Ｃ２，晶胞参数为：ａ＝１２．０４４（１），ｂ＝１２．２２４（２），ｃ＝１１．８６８（１）；β＝１０８．０４°；Ｚ＝２，Ｒ１＝０．０３８４，ｗＲ２＝０．０５１６。在配合物正离子中，咪唑桥联两个等价的（２，３，２）Ｎｉ，每个镍原子都有四方锥的配位环境，（２，３，２）的四个配位Ｎ原子构成赤道平面，咪唑Ｎ原子占据轴向位置，分子内两个金属间的距离为６．１９０（３）
In this paper, two novel complexes of bis (2-aminoethyl) -1,3-propanediamine [abbreviated as (2,3,2)] with nickel are reported: ) 2] (ClO4) 2 and [(2,3,2) 2Ni2 (Im)] (ClO4) 3 where ImH is imidazole. The complex [(2,3,2) Ni (ImH2)] (ClO4) 2 belongs to the orthorhombic space group Pna21 with unit cell parameters of a = 16.798 (3) and b = 15.724 ), C = 8.891 (2) , Z = 2. R1 = 0.0566, wR2 = 0.0659. In the complex positive ions, Ni and two coordination N atoms of (2,3,2) and two coordination N atoms of two imidazoles form the octahedral coordination structure of NiN6, (2,3,2 Take the cis conformation. The complex [(2,3,2) 2Ni2 (Im)] (ClO4) 3 belongs to the monoclinic system with space group C2. The unit cell parameters are a = 12.044 (1), b = 12.224 ), C = 11.868 (1) ; β = 108.04 °; Z = 2, R1 = 0.0384, wR2 = 0.0516. In complex cations, imidazole bridges two equivalent (2,3,2) Ni, each nickel atom has a tetragonal pyramid coordination environment, (2,3,2) four coordination N Atoms constitute the equatorial plane, the imidazole N atoms occupy the axial position, the distance between the two metals in the molecule is 6.190 (3)