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在温和的反应条件下合成了聚2-乙炔基N-己基吡啶。反应是通过直接聚合2-乙基吡啶和相对应的N-己基卤化物完成的。聚合过程既不需要任何的起始条件也不需要催化剂。聚合反应的聚合物产率很高。聚合物结构是具有N-己基吡啶分支的共轭结构。测量了聚合物的光电性能。当光电子能量为2.06eV时,PEHPB的光致发光峰出现在603nm处。
Poly-2-ethynyl-N-hexylpyridine was synthesized under mild reaction conditions. The reaction is carried out by direct polymerization of 2-ethylpyridine and the corresponding N-hexyl halide. The polymerization process does not require any starting conditions nor a catalyst. Polymerization yield of polymer is high. The polymer structure is a conjugated structure with N-hexylpyridine branches. The photoelectric properties of the polymer were measured. When the photoelectron energy is 2.06 eV, the photoluminescence peak of PEHPB appears at 603 nm.