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A needle-like Eu2+ and Dy3+ co-doped BaAl2O4 long-lasting phosphor was synthesized via a hydrothermal-homogeneous precipitation method assisted by cetyl trimethyl ammonium bromide(CTAB) as a template.The crystal structure,morphology and optical properties of the composites were characterized.XRD results showed that the single-phase BaAl2O4 was formed at 900 ℃ in an active carbon atmosphere,which was much lower than that prepared by traditional solid-state reaction method.Scanning electron microscopy(SEM) and transmission electron microscopy(TEM) observation revealed that the precursor had well-dispersed distribution and showed needle-like morphology with the average diameter of about 100 nm and the length up to 1 μm.The final product,BaAl2O4:Eu2+,Dy3+ phosphor,inherited the needle-like shape from precursor via adding the surfactant CTAB.After irradiation by ultraviolet radiation with 355 nm for 5 min,the phosphors emitted bluish green color long-lasting phosphorescence corresponding to the typical emission of Eu2+ ion.Both the photoluminescence spectra and luminance decay revealed that the phosphor had efficient luminescent and long-lasting properties.
A needle-like Eu2 + and Dy3 + co-doped BaAl2O4 long-lasting phosphor was synthesized via a hydrothermal-homogeneous precipitation method assisted by cetyl trimethyl ammonium bromide (CTAB) as a template. Crystal structure, morphology and optical properties of the composites were . XRD results showed that the single-phase BaAl 2 O was formed at 900 ℃ in an active carbon atmosphere, which was much lower than that prepared by conventional solid-state reaction method. Scanning electron microscopy (SEM) and transmission electron microscopy revealed that the precursor had well-dispersed distribution and showed needle-like morphology with the average diameter of about 100 nm and the length up to 1 μm. The final product, BaAl2O4: Eu2 +, Dy3 + phosphor, inherited the needle- like shape from precursor via adding the surfactant CTAB.After irradiation by ultraviolet radiation with 355 nm for 5 min, the phosphors emitted bluish green color long-lasting phosphorescence corresponding to the typical emission of Eu2 + ion.Both the photoluminescence spectra and luminance decay revealed that the phosphor had efficient luminescent and long-lasting properties.