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合成了冠醚化钴（Ⅱ）Ｓｃｈｉｆ碱配合物１ｃ及其相关类似物１ｂ，测定了它们的氧加合常数，考查了它们对异丙苯的催化氧化性能，并与未冠醚化的类似物１ａ作比较，讨论了１ｃ分子中的冠环对催化氧化性能的影响
The crown etherified cobalt (Ⅱ) Schiff base complex 1c and its related analogues 1b were synthesized and their oxygenation constants were determined. The catalytic oxidation of cumene was investigated and compared with the uncoronal etherification The comparison of 1a, the effect of the crown ring in 1c on the catalytic oxidation performance was discussed