Synthesis and characterization of star-comb polybutadiene and poly(ethylene-co-butene)

来源 :Chinese Chemical Letters | 被引量 : 0次 | 上传用户:yaci
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A novel star-comb polybutadiene(SC-PB) was synthesized with n-butyllithium(n-BuLi) as initiator,epoxidized star liquid polybutadiene(ESPB) as coupling agent,cyclohexane as solvent by living anionic polymerization and grafting-onto technology. The SC-PB was subsequently hydrogenated by homogeneous catalysis(catalytic hydrogenation using nickel naphthenate/ triisobutyl aluminum),to transform the SC-PB into the corresponding star-comb poly(ethylene-co-butene)(SC-PEB).The SC-PB was characterized by SEC-TALLS,~1H NMR,DSC and WAXD techniques.The hydrogenation degree and crystallinity degree of SC-PEB were also determined. A novel star-comb polybutadiene (SC-PB) was synthesized with n-butyllithium (n-BuLi) as initiator, epoxidized star liquid polybutadiene (ESPB) as coupling agent, cyclohexane as solvent by living anionic polymerization and grafting-onto technology. SC-PB was followed by hydrogenated by homogeneous catalysis (catalytic hydrogenation using nickel naphthenate / triisobutyl aluminum), to transform the SC-PB into the corresponding star-comb poly was characterized by SEC-TALLS, ~ 1H NMR, DSC and WAXD techniques. The hydrogenation degree and crystallinity degree of SC-PEB were also determined.
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