本文基于在国家自然科学基金“创新研究群体”资助项目的研究成果,分别从活泼的含系列五边形的富勒烯、具有高对称性和开普勒结构的金属簇合物、高指数活性晶面裸露的纳米晶体等方面介绍了新型团簇及其相关纳米材料合成的研究进展,并综述了它们的性能和应用前景。这些研究成果在国际学术界产生重要影响,并带动了相关领域研究的发展。 Based on the research results funded by the National Natural Science Foundation of China and the “Innovative Research Groups”, this paper presents a series of studies on the effects of fullerenes, pentacyclic fullerenes, metal clusters with high symmetry and Kepler structures, Exponential active crystal surface naked nanocrystals and so on. The progress of the synthesis of new clusters and their related nanomaterials is introduced, and their properties and application prospects are reviewed. These research results have a significant impact in the international academic community and have led to the development of research in related fields.