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Antweiler在1939年首先将悬汞电极应用于极谱极大的研究,后来又被许多化学工作者引入不同的研究之中,例如它被用于研究伏-安曲线,双电层的微分电容,电极反应动力学,以及有机化合物的极谱性质等。在1956年以后这种电极才被应用于分析化学之中,自阳极溶出分析出现和发展以后,就被广泛地用于测定纯材料中数量级为10~(-6)—10~(-9)克分子的微量杂质,在适宜的条件下灵敏度甚至可以达到10~(-11)克分子/升。这种方法不但在最大灵敏度上比一般常用于微量杂质分析的方波极谱法、矢量极
In 1939, Antweiler firstly applied the hanging mercury electrode to the polarographic research, and later it was introduced into many different studies by many chemists. For example, it was used to study voltammetry curves, the differential capacitance of an electric double layer, Electrode reaction kinetics, as well as the polarographic nature of organic compounds. Since 1956, the electrodes have been used in analytical chemistry. Since the appearance and development of anodic dissolution analysis, they have been widely used in the determination of pure materials in the order of 10 -6 -6 -10 -9. Molecular trace impurities, under the appropriate conditions, the sensitivity can reach 10 ~ (-11) mol / liter. This method not only in the maximum sensitivity than the commonly used for trace impurity analysis of square wave polarography, vector pole