In this study ,the electronic transition properties and structural analysis of the metal complexes (Ni (Ⅱ) ,Co(Ⅱ) ,Cu(Ⅱ) and M n(Ⅱ)) of three different polymer ligands were performed by using XRF and X‐ray diffraction (XRD ) techniques ,respectively .T he structural analysis of the polymers and their complexes were performed by XRD technique and some of the polymers were found to be in the face‐centred cubic (fcc) structure .In addition ,the values of the present K X‐ray intensity ratios are significantly greater than the val‐ues reported in literature .