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在溶剂热条件下,MnCl2·4H2O,四氮唑-1-乙酸(1-tza)和邻菲罗啉(phen)在乙腈溶剂中反应得到一个新型单核配合物[Mn(1-tza)2(phen)2]·H2O(1),该配合物通过氢键作用在ab面形成一维链状超分子结构,链与链之间又通过π-π堆积形成二维层状超分子结构.配合物1的晶体数据为:C30H24MnN12O5,M=687.55,空间群为P2(1),a=9.163 10(10),b=15.475 5(2),c=21.446 7(2),α=γ=90°,β=101.79°,V=2 977.04(6)3,z=4,Dc=1.534 Mg/m3,R1=0.046 8,wR2=0.136 2.
In solvothermal condition, MnCl2 · 4H2O, tetrazole-1-acetic acid (1-tza) and phenanthroline were reacted in acetonitrile solvent to obtain a new mononuclear complex [Mn (phen) 2] · H2O (1). The complex forms a one-dimensional chain-like supramolecular structure on the ab plane by hydrogen bonding and forms a two-dimensional layered supramolecular structure by the π-π stacking between the chains. The crystal data of complex 1 are: C30H24MnN12O5, M = 687.55, space group P2 (1), a = 9.163 10 (10) , b = 15.475 5 (2) and c = 21.446 7 = γ = 90 °, β = 101.79 °, V = 2 977.04 (6) 3, z = 4, Dc = 1.534 Mg / m3, R1 = 0.046 8, wR2 = 0.136 2.