利用自制的蒸汽氧化装置对不同晶粒度和表面状态的S30432钢管试样在650℃下进行不同试验时间节点的蒸汽氧化试验,采用光学显微镜、扫描电镜和X射线衍射等分析方法研究了氧化层的形貌、成分和相组成.结果表明:在试验时间内,不同的S30432钢管试样的抗蒸汽氧化性能存在差异;细化晶粒及提高晶粒度均匀性有利于提高S30432钢的抗蒸汽氧化性能;喷丸处理能改变钢管试样的内壁表面状态,加快Cr从基体向内壁表面扩散,形成富Cr的致密氧化层,显著降低了氧化膜的生长速度;在蒸汽氧化过程中形成的氧化层分内外两层:内层富Cr,与基体界面处形成高铬含量愈合层,外层为铁的氧化物. The steam oxidation test of S30432 steel tube specimens with different grain size and surface condition at 650 ℃ was carried out by using self-made steam oxidation equipment. The effects of the oxide layer The results showed that the resistance to steam oxidation of different S30432 steel pipe samples was different during the test period. The grain refinement and the improvement of the uniformity of grain size were beneficial to the improvement of steam resistance of S30432 steel The performance of the shot peening can change the surface state of the inner wall of the steel pipe sample and accelerate the diffusion of Cr from the substrate to the inner wall surface to form a Cr-enriched dense oxide layer and significantly reduce the growth rate of the oxide film. The oxidation Layer inside and outside the two layers: the inner layer of Cr-rich, with the formation of high chromium matrix healing layer interface, the outer layer of iron oxide.