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Compound [Co 3(BTC)(HBTC)(H 2BTC)(C 2H 4O 2) 3]·3(DMF)·6(H 3O) was synthesized under mild conditions and its crystal structure was determined by using single crystal X-ray diffraction. The crystal structure was solved by direct method and refined by full-matrix least-square method. The crystal is monoclinic and belongs to space group Cc with a=2.645 3(5) nm, b= 1.670 4(3) nm, c=1^821 6(4) nm, β=128.16(3) °, V=6.329(2) nm 3, Z=2 , D c=20.200 Mg/m 3, M r= 1 314.744, μ=10.274 mm -1, F(000) =38 226, GOF=0.99, R=0.094 1, ωR=0.257 3.
Compound [Co 3 (BTC) (HBTC) (H 2BTC) (C 2H 4O 2) 3] · 3 (DMF) · 6 (H 3 O) was synthesized under mild conditions and its crystal structure was determined by using single crystal X- ray diffraction. The crystal structure was solved by direct method and refined by full-matrix least-square method. The crystal is monoclinic and belongs to space group Cc with a = 2.645 3 (5) nm, b = 1.670 4 , c = 1 ^ 821 6 (4) nm, β = 128.16 (3) °, V = 6.329 (2) nm 3, Z = 2, D c = 20.200 Mg / m 3, M r = 1 314.744, μ = 10.274 mm -1, F (000) = 38 226, GOF = 0.99, R = 0.094 1, ωR = 0.257 3.