论文部分内容阅读
Carbon nanotube(CNTs)/Fe-Ni/TiO_2 nanocomposite photocatalysts have been synthesized by an in situ fluidized bed chemical vapor deposition(FBCVD) method.The composite photocatalysts were characterized by XRD,Raman spectroscopy,BET,FESEM,TEM,UV-vis spectroscopy,and XPS.The results showed that the CNTs were grown in situ on the surface of TiO_2.Fe(lll) in TiO_2 showed no chemical changes in the growth of CNTs.Ni(Ⅱ) was partly reduced to metal Ni in the FBCVD process,and the metal Ni acted as a catalyst for the growth of CNTs.The photocatalytic activities of CNTs/Fe-Ni/TiO_2 decreased with the rise of the FBCVD reaction temperature.For the sample synthesized at low FBCVD temperature(500℃),more than 90% and nearly 50% of methylene blue were removed under UV irradiation in 180 min and under visible light irradiation in 300 min,respectively.The probable mechanism of synergistic enhancement of photocatalysis on the CNTs/Fe-Ni/TiO_2 nanocomposite is proposed.
Carbon nanotube (CNTs) / Fe-Ni / TiO 2 nanocomposite photocatalysts have been synthesized by an in situ fluidized bed chemical vapor deposition (FBCVD) method. The composite photocatalysts were characterized by XRD, Raman spectroscopy, BET, FESEM, TEM, UV-vis spectroscopy, and XPS. The results showed that the CNTs were grown in situ on the surface of TiO_2.Fe (lll) in TiO_2 showed no chemical changes in the growth of CNTs.Ni (II) was partly reduced to metal Ni in the FBCVD process, and the metal Ni acted as a catalyst for the growth of CNTs. The photocatalytic activities of CNTs / Fe-Ni / TiO 2 decreased with the rise of the FBCVD reaction temperature. For the sample synthesized at low FBCVD temperature (500 ° C.) more than 90% and nearly 50% of methylene blue were removed under UV irradiation in 180 min and under visible light irradiation in 300 min, respectively. The probable mechanism of synergistic enhancement of photocatalysis on the CNTs / Fe-Ni / TiO 2 nanocomposite is proposed .