【摘 要】
：
Molybdenum dinitrogen complexes supported by monodentate arylsilylamido ligand,[Ar(Me3Si)N]3MoN2Mg(THF)2[N(SiMe3)Ar](5) and[Ar(Me3Si)N]3MoN2SiMe3 (6)(Ar =3,5-Me2C6H3) were synthesized and structurally characterized,and proved to be effective catalysts for
【机 构】
：
Department of Chemistry,Fudan University,Shanghai 200433,China;Department of Chemistry,Fudan Univers
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Molybdenum dinitrogen complexes supported by monodentate arylsilylamido ligand,[Ar(Me3Si)N]3MoN2Mg(THF)2[N(SiMe3)Ar](5) and[Ar(Me3Si)N]3MoN2SiMe3 (6)(Ar =3,5-Me2C6H3) were synthesized and structurally characterized,and proved to be effective catalysts for the disproportionation of cyclohexadienes and isomerization of terminal alkenes.The 1H NMR spectrum suggested that the bridging nitrogen ligand remains intact during the catalytic reaction,indicating possible catalytic ability of the Mo-N=N motif.
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