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研究了配位原子为氮或氮硫的５种新型功能性树脂对Ｒｕ（Ⅳ）的吸附行为（３－氨甲基吡啶树脂（３－ＡＭＰＲ）、吡唑树脂（ＰＡＺＲ）、２－氨甲基吡啶树脂、Ｎ－甲基－２－硫咪唑树脂、２－硫－苯骈咪唑树脂的功能基（ＦＧ）含量为３．１６～４．８７ｍｍｏｌＦＧ／ｇ树脂），以及酸度、温度、时间对吸附的影响。测定其吸附容量、吸附比、吸附速率常数、吸附熵、分配系数和洗脱率等参数。３－ＡＭＰＲ有最高的吸附容量１．６４ｍｍｏｌＲｕ（Ⅳ）／ｇ３－ＡＭＰＲ和最低的吸附比１．９４ＦＧ／Ｒｕ（Ⅳ）（摩尔比）。吸附在ＰＡＺＲ上的Ｒｕ（Ⅳ）可被５％硫脲水溶液：丙酮：盐酸＝１：１：２（体积比）的混合溶液洗脱，洗脱率１００．３％。化学法，红外谱图阐明了树脂吸附Ｒｕ（Ⅳ）的机理。
The adsorption behavior of Ru (Ⅳ) to 5 new functional resins with coordination atoms of nitrogen or nitrogen and sulfur (3-aminomethylpyridine resin (3-AMPR), pyrazole resin (PAZR) (FG) content of 3.16 ~ 4.87 mmol FG / g resin), and the acidity, temperature, time Adsorption effects. The adsorption capacity, adsorption ratio, adsorption rate constant, adsorption entropy, partition coefficient and elution rate were measured. 3-AMPR has the highest adsorption capacity of 1.64mmolRu (Ⅳ) / g3-AMPR and the lowest adsorption ratio of 1.94FG / Ru (Ⅳ) (molar ratio). Ru (Ⅳ) adsorbed on PAZR was eluted with a mixed solution of 5% thiourea aqueous solution: acetone: hydrochloric acid = 1: 1: 2 (volume ratio) Chemical and infrared spectra elucidated the mechanism of resin adsorption of Ru (Ⅳ).