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用流变相反应法合成了Ni(OH)Sal·H2 O和Ni2 (OH) 2 Sal2 ·H2 O。通过元素分析、TG、IR、XRD和磁矩对其结构进行了分析。结果表明两个配合物都属于单斜晶系 ,其晶胞参数为 ,Ni(OH)Sal·H2 O∶a =13.1179,b =11.36 41,c =9.5 6 0 5 ,β =92 .96 2 ,V =14 2 3.31(97) 3,Z =7,Dcalcd .=1.885 g/cm3,Dexpt=1.85 8g/cm3;Ni2 (OH) 2 Sal2 ·H2 O :a =13.12 17,b =11.35 80 ,c =9.5 5 2 2 ,β =92 .978 ,V =14 2 1.72 (95 ) 3,Z =4 ,Dcalc=2 .0 73g/cm3,Dexp=2 .0 0 0 g/cm3。
Ni (OH) Sal · H 2 O and Ni2 (OH) 2 Sal2 · H 2 O were synthesized by the rheological phase reaction method. Its structure was analyzed by elemental analysis, TG, IR, XRD and magnetic moment. The results show that both complexes belong to the monoclinic system with unit cell parameters of Ni (OH) Sal · H 2 O: a = 13.1179, b = 11.36 41, c = 9.5 6 0 5, β = 92.962 , V = 14 2 3.31 (97) 3, Z = 7, Dcalcd. = 1.885 g / cm 3, Dexpt = 1.85 8 g / cm 3, Ni 2 (OH) 2 Sal 2 .H 2 O: a = 13.12 17, b = 11.35 80, c = 9.5 5 2 2, β = 92 .978, V = 14 2 1.72 (95) 3, Z = 4, Dcalc = 2.073 g / cm 3, and Dexp = 2.000 g / cm 3.