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2,9-Diformyl-1,10-phenanthrolinebis(2,6-dimethylanil)cobalt(II) perchlorate was synthesized and demonstrated to be [CoL2][ClO4]2 by X-ray diffraction analysis. It crystallizes in the monoclinic system, space group C2/c with a = 22.294(4), b = 15.122(3), c = 20.640(4) , β = 119.618(4)°, V = 6048.9(19) 3, C63H52Cl2CoN9O9, Mr = 1208.97, F(000) = 2504, Dc = 1.328g/cm3, Z = 4, μ = 0.436, the final R = 0.0712 and wR = 0.1718 for 1734 observed reflections (I > 2σ(I)). In its solid state the helical polymeric chains are supramolecularly associated through intermolecular and inter- ionic hydrogen bonding interactions.
2,9-Diformyl-1,10-phenanthrolinebis (2,6-dimethylanil) cobalt (II) perchlorate was synthesized and demonstrated to be [CoL2] [ClO4] 2 by X-ray diffraction analysis. It crystallizes in the monoclinic system, Space group C2 / c with a = 22.294 4, b = 15.122 3, c = 20.640 4, β = 119.618 4, V = 6048.9 19, C63H52Cl2CoN9O9, Mr = 1208.97, F (000) = 2504, Dc = 1.328g / cm3, Z = 4, μ = 0.436, the final R = 0.0712 and wR = 0.1718 for 1734 observed reflections (I> 2σ (I)). chains are supramolecularly associated through intermolecular and inter-ionic hydrogen bonding interactions.