使用光学活性的2-氨基丁醇-1、麻黄素、ψ-麻黄素、酒石酸和谷氨酸在KF·2H_2O存在下分别与Merrifield树脂反应制得8种相应的手征性树脂.由这些树脂和Cu(NO_3)_2作用后生成的Cu(Ⅱ)络合物树脂作为氧化偶合试剂,对2-萘酚的氧化偶合反应具有立体选择效果,可得致电46～58ee%的(+)-或(-)-1,1′-联-2-萘酚。 Eight corresponding chiral resins were prepared by reacting optically active 2-aminobutanol-1, ephedrine, ψ-ephedrine, tartaric acid and glutamic acid with Merrifield resin in the presence of KF · 2H 2 O. These resins And Cu (Ⅱ) complex resin formed after the action of Cu (NO_3) _2 were used as the oxidative coupling reagent, which had stereoselective effect on the oxidative coupling reaction of 2-naphthol. (-) - 1,1’-bi-2-naphthol.