【摘 要】
：
The new complexes, [PdCl{C5H4FeC5H4CHRN=CHC4H3O}(Ph3P)] (R= H, CH3) were synthesized via two novel Schiff bases (C5H5FeC5H4CHRN=CHC4H3O, R= H, CH3) with lithium
【出 处】
：
Chinese Chemical Letters
论文部分内容阅读
The new complexes, [PdCl{C5H4FeC5H4CHRN=CHC4H3O}(Ph3P)] (R= H, CH3) were synthesized via two novel Schiff bases (C5H5FeC5H4CHRN=CHC4H3O, R= H, CH3) with lithium tetrachloropalladate (II), and characterized by IR, elemental analysis, 1H NMR. Complex 5a was further determined by X-ray single crystal diffraction. We found that it contained an intramolecular N→Pd coordination in the compound 5a, and the palladium atom was bound to the unsubstituted Cp ring. The Pd-N, Pd-C (1) and Pd-O bond lengths were 2.121 (3), 2.008 (4) and 2.990 ?, respectively.
The new complexes, [PdCl {C5H4FeC5H4CHRN = CHC4H3O} (Ph3P)] (R = H, CH3) were synthesized via two novel Schiff bases (C5H5FeC5H4CHRN = CHC4H3O, R = H, CH3) with lithium tetrachloropalladate (II) IR, elemental analysis, 1H NMR. Complex 5a was further determined by X-ray single crystal diffraction. We found that it contained an intramolecular N → Pd coordination in the compound 5a, and the palladium atom was bound to the unsubstituted Cp ring. Pd-N, Pd-C (1) and Pd-O bond lengths were 2.121 (3), 2.008 (4) and 2.990 ?, respectively.
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