Lithium(Li)metal has been regarded as one of the most promising candidates to replace graphite anode due to its high theoretical specific capacity and the lowest electrochem-ical potential[1-3].However,the immoderate growth of Li dendrite during Li plating/stripping causes serious safety problem and poor performance that severely impedes the practical application of lithium metal batteries(LMBs)[4-6].Until now,there have been numerous kinds of strategies be proposed to inhibit Li dendrites growth and protect lithium metal anode such as high concentration electrolytes[7],con-struction of the solid electrolyte interface layer[8],structural design of anode materials[9],regulation of Li+solvation[10],and solid-state electrolytes[11].As an important part of battery structure,separator plays a vital role in the perfor-mance of battery[12].The main function of separator is to divide the anode and cathode that prevents internal short cir-cuit caused by direct contact between anode and cathode.So,the separator needs to be electrically insulated.At the same time,the separator also needs to ensure that the electrolyte is conductive between anode and cathode[13].Therefore,it is necessary to render the separator fully wetted.Nevertheless,there are few researches on enhancing the wettability of the separator especially functional electrolyte additives.