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沸石微孔晶体材料作为客体功能物种的主体材料在主-客体组装化学中发挥着越来越重要的作用,在微型激光器、非线性光学、生物成像、光放大及光显示等高技术领域已显示出广阔、诱人的发展前景.本文介绍国内外,特别是河北工业大学在稀土/L型沸石主-客体杂化功能材料的组装、结构及其发光性能的研究工作,具体包括:稀土有机配合物在L沸石孔道内的组装、L型沸石-有机高分子透明杂化发光材料的制备及稀土有机配合物诱导控制的L型沸石自组装等.此外,本文对稀土/L型沸石主-客体杂化发光功能材料的研究进行了展望.
Zeolite microporous crystal materials, as the host material of guest functional species, play an increasingly important role in host-guest assembly chemistry and have been shown in the fields of high-tech fields such as micro-lasers, nonlinear optics, bioimaging, optical amplification and light display A vast and attractive prospect of development.In this paper, the research work on the assembly, structure and luminescent properties of host-guest hybrid functional materials at home and abroad, especially at Hebei University of Technology, are described in detail, including: L zeolite-organic hybrid transparent hybrid luminescent material and the self-assembly of L-type zeolite controlled by rare earth organic complex etc.In addition, the main-guest of the rare earth / L zeolite The research of hybrid luminescent functional materials is prospected.