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在温和反应条件下,铜催化间隔烯炔衍生物与有机硅烷硼酸酯化合物发生反应,通过调控有机硅硼试剂的用量,以较高产率分别制备共轭乙烯基联烯硅和1,3-共轭二烯硅产物.该方法为制备多取代立体选择性官能团化联烯和1,3-共轭二烯产物提供了简单、高效的合成工具.
铜催化共轭乙烯基联烯硅和1,3-二烯硅合成
【摘 要】
：
在温和反应条件下,铜催化间隔烯炔衍生物与有机硅烷硼酸酯化合物发生反应,通过调控有机硅硼试剂的用量,以较高产率分别制备共轭乙烯基联烯硅和1,3-共轭二烯硅产物.该方法为制
【机 构】
：
中国科学技术大学化学与材料科学学院,安徽合肥230026
【出 处】
：
分子科学学报
【发表日期】
：
2021年2期
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