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分别测定了PAC电极(Pb-Ag-Ca新型阳极的简称)在MnSO4-H2SO4溶液中的阴极极化曲线(以~lgi作图)及阳极极化曲线,从图中求得:icor=15.85μA/cm2,cor=-0095v,Vcor=2.95Kg/m2ann.7.09%(电极重量每年消耗的百分数)io(2)=54.70μA/cm2及io(3)=1.10μA/cm2;讨论了PAC阳极的腐蚀机理即反应(2)受反应(3)的动力学参数所控制,为EMD工业中使用该阳极提供基础性数据.
The cathodic polarization curve (plotted as ~ lgi) and the anodic polarization curve of the PAC electrode (short for Pb-Ag-Ca new anode) in MnSO4-H2SO4 solution were determined. 85μA / cm2, cor = -0095v, Vcor = 2.95Kg / m2ann. 7.09% (the percentage of electrodes consumed per year) io (2) = 54.70μA / cm2 and io (3) = 1.10μA / cm2. The corrosion mechanism of PAC anode was discussed. ) Kinetic parameters, providing the foundational data for the use of the anode in the EMD industry.