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Hydrothermal reactions of biphenyl-2,3,3?,5?-tetracarboxylic acid(H4bptc) with cobalt salt in the presence of 1,4-bis(2-pyridylmethyl)piperazin(bpmp) afforded one novel coordination polymer, namely, [Co(H2bptc)(bpmp)0.5(H2O)]n(1). Its structure was establ