Electrostatic Self-assembly of 0D-2D SnO2 Quantum Dots/Ti3C2Tx MXene Hybrids as Anode for Lithium-Io

来源 :纳微快报(英文) | 被引量 : 0次 | 上传用户:yaojian42506
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
MXenes,a new family of two-dimensional (2D) materials with excellent electronic conductivity and hydrophilicity,have shown distinctive advantages as a highly conductive matrix material for lithium-ion battery anodes.Herein,a facile electrostatic self-assembly of SnO2 quantum dots (QDs) on Ti3C2Tx MXene sheets is proposed.The as-prepared SnO2/MXene hybrids have a unique 0D-2D structure,in which the 0D SnO2 QDs (~4.7 nm) are uniformly distributed over 2D Ti3C2Tx MXene sheets with controllable loading amount.The SnO2 QDs serve as a high capacity provider and the spacer to prevent the MXene sheets from restacking;the highly conductive Ti3C2Tx MXene can not only provide efficient pathways for fast transport of electrons and Li ions,but also buffer the volume change of SnO2 during lithiation/delithiation by confining SnO2 QDs between the MXene nanosheets.Therefore,the 0D-2D SnO2 QDs/MXene hybrids deliver superior lithium storage properties with high capacity (887.4 mAh g-1 at 50 mA g-1),stable cycle performance (659.8 mAh g-1 at 100 mA g-1 after 100 cycles with a capacity retention of 91%) and excellent rate performance (364 mAh g-1 at 3 A g-1),making it a promising anode material for lithium-ion batteries.
其他文献
由于石墨烯的特殊半导体性质,实现其在电子器件中实际应用的关键是对石墨烯层进行微纳结构处理。简单介绍了飞秒四光束干涉技术应用于石墨烯微纳加工的优势。对实现飞秒四光
目的观察玻璃体腔注射脂质体介导的过氧化物酶增殖激活受体-γ共激活子-1α(PGC-1α)特异性小干扰RNA(siRNA)对小鼠视网膜新生血管的抑制作用。方法80只C57BL/6J小鼠分为正常组、模型空白组、模型对照组和PGC-1α siRNA组,每组20只。正常组小鼠在正常空气中饲养。模型空白组、模型对照组和PGC-1α siRNA组小鼠建立氧诱导视网膜病变模型。小鼠12日龄时,模型对照组、PGC
近几年来,Skyline查询处理在许多应用领域具有潜在的实用价值。在Map-Reduce框架下采用基于角度数据划分的方法,本文提出Cirl-Skyline查询算法。进一步提高算法的查询效率,为了更好的解决重复计算局部没有发生变化Skyline查询点的问题,在Cirl-Skyline算法的基础上提出Restrict-Skyline算法。理论分析和实验证实,该算法具有高效性和可扩展性。
【摘 要】当前,随着新课改的不断深入,越来越多的专家学者关注到运用分层教学,提升课堂教学有效性的重要性,对于我们初中体育学科来讲更是如此,但是对于初中体育方面进行分层教学的研究还是较少的。因此,本人通过查阅大量的文献资料,并结合自身从事多年初中体育学科教学实际入手,分三个部分进行探讨,希望能为优化课堂教学,提升教学有效性提供一定的参考。  【关键词】初中体育 分层教学 课堂教学 有效性  一、因材
Zeolitic imidazolate frameworks (ZIFs) as smart drug delivery systems with microenvironment-triggered release have attracted much attention for tumor therapy.Ho
Na-ion batteries (NIBs) have attracted considerable attention in recent years owing to the high abundance and low cost of Na.It is well known that S doping can
Rational design of hybrid carbon host with high electrical conductivity and strong adsorption toward soluble lithium polysulfides is the main challenge for achi
在硅通孔(through silicon via,TSV)的铜互连技术中,对于阻挡层的抛光,Ti和Cu去除速率非常重要。实验中采用的阻挡层材料为Ti,主要研究了pH值和氧化剂(H2O2)对Ti和Cu去除速率
Tumor-derived exosomes are actively involved in cancer progression and metastasis and have emerged as a promising marker for cancer diagnosis in liquid biopsy.B
Metallic Sn has provoked tremendous progress as an anode material for sodium-ion batteries (SIBs).However,Sn anodes suffer from a dramatic capacity fading,owing