The resources-oriented industry cluster is geographically close to natural resources development and processing industry. The knowledge-intensive, technology-intensive, capital-intensive, and labor-intensive is a relatively aggregate associated with natural resources and will structure commonality and complementary coupling so that economic and social development play a leading role in the complex adaptive systems closely related to ecological environment. A resources-oriented industry cluster in Yunnan has general common characteristics of industrial clusters and will form the characteristics of the enterprise spatial aggregation of innovative network of the industrial chain and value chain. According to the market structure of resources and resources market behavior in Yunnan, the particularity of resources commodity production has conduced resources market structure and general merchandise market structure many differences. Optimizing the cluster structure and extending the industrial chain have improved the productivity of the cluster and extension the lifecycle of the cluster to achieve sustainable development.